What is ODT?
What LibreOffice, OpenOffice and Google Docs save a document as, and the ISO-standard counterpart to .docx. Inside it is a zip of XML, which is the reason a table drawn in one can be read back out at all. It is a page format first - paragraphs, page breaks, headers, footnotes - so the only part of it that is data is a table someone drew on the page.
What is XLSX?
A modern Excel workbook, which is really a zip full of XML. Unlike a CSV it knows what a number is, holds multiple sheets, and keeps formulas and formatting. It's what people mean when they say 'send me a spreadsheet'.