What is AVIF?
Built on the AV1 video codec, and the smallest of the widely-supported image formats by a clear margin - frequently half the size of a JPG that looks the same. It handles transparency and HDR. Being new is its only real drawback: plenty of software still won't open one.
What is ICNS?
Apple's icon container, the thing inside every .app bundle that makes it look like something. Like ICO it holds a set of sizes, but it goes considerably larger - Retina displays ask for 1024px icons, which Windows never did.