What is DDS?
DDS is DirectDraw Surface, the texture format games ship. Its point is that the GPU reads the compressed blocks directly, so BC1/BC3 textures never need unpacking at runtime. FileSorcery reads it and converts out; writing good block compression is a job for a dedicated compressor.
What is TGA?
Truevision TGA is a fixture of game development and 3D texturing, where its straightforward layout and real alpha channel have kept it in use long after browsers stopped caring about it. Files may be raw or run-length encoded.