What is ICO?
Windows icons, and a container rather than an image - one file holds the same icon at several sizes, so Windows can pick the right one for a title bar or a desktop. It tops out at 256x256 and supports transparency, which is what stops an icon looking like a sticker.
What is PBM?
One bit per pixel - black or white, nothing in between. The most minimal image format in common use, and still the right one for scanned documents, line art and anything headed into OCR or shape analysis. Photographs do not survive it.